LC_FF0490

Pesticides on Ultra Aqueous C18

	Peaks	RT (min)	Transition 1	Transition 2
1.	Acephate	1.27	184.1 -> 143	184.1 -> 125
2.	Acetamiprid	4.44	223.2 -> 126.1	223.2 -> 99.1
3.	Acibenzolar-S-methyl	7.22	211 -> 136	211 -> 140
4.	Alanycarb	7.91	400.1 -> 238.2	400.1 -> 91.1
5.	Aldicarb	4.49	208.2 -> 116.1	208.2 -> 89.1
6.	Aldicarbsulfone	2.03	223.1 -> 86.1	223.1 -> 148
7.	Aldicarbsulfoxide	2.2	207.1 -> 132.1	207.1 -> 89.1
8.	Ametryn	6.96	228.1 -> 186.1	228.1 -> 96
9.	Aminocarb	5.37	209.1 -> 137.1	209.1 -> 152.1
10.	Avermectin B1a	11.2	890.5 -> 305	890.5 -> 145
11.	Avermectin B1b	11.4	876.5 -> 291	876.5 -> 145
12.	Azoxystrobin	6.78	404.1 -> 372.1	404.1 -> 344.1
13.	Benalaxyl	7.78	326.2 -> 148.2	326.2 -> 91.1
14.	Bendiocarb	5.1	224.2 -> 109.2	224.2 -> 167.2
15.	Benfuracarb	8.33	411.2 -> 195.1	411.2 -> 252.1
16.	Benthiavalicarb	6.87	382.1 -> 116	382.1 -> 180.1
17.	Benthiavalicarb-isopropyl	6.87	382.1 -> 196.8	382.1 -> 179.9
18.	Benzoximate	7.98	364 -> 199	364 -> 105
19.	Bitertanol	7.98	338 -> 70	338 -> 269
20.	Boscalid	6.98	343 -> 307	343 -> 140
21.	Bromuconazole (isomer 1)	7.36	378 -> 159.1	378 -> 161
22.	Bromuconazole (isomer 2)	8.05	378.1 -> 159.1	378.1 -> 161
23.	Bufencarb	5.18	222.2 -> 95.1	222.2 -> 71
24.	Bupirimate	7.65	317 -> 166	317 -> 108
25.	Buprofezin	8.53	306.2 -> 201.1	306.2 -> 116.2
26.	Butafenacil	7.08	492.2 -> 331.1	492.2 -> 180.1
27.	Butocarboxim	4.4	191.1 -> 75	191.1 -> 116
28.	Butocarboximsulfoxid	2.1	207 -> 74.9	207 -> 90
29.	Butoxycarboxim	1.95	223.1 -> 106	223.1 -> 166
30.	Carbaryl	5.63	202.1 -> 145	202.1 -> 127
31.	Carbendazim	4.52	192.2 -> 160.2	192.2 -> 132.1
32.	Carbetamide	4.74	237 -> 192	237 -> 118
33.	Carbofuran	5.18	222.2 -> 123.1	222.2 -> 165.2
34.	Carboxine	5.61	236 -> 143	236 -> 87
35.	Carfentrazone-ethyl	7.53	412 -> 346	412 -> 366
36.	Chlorfluazuron	9.18	540 -> 158	540 -> 519.7
37.	Chloroxuron	7.53	291 -> 72	291 -> 218
38.	Chlorpyrifos	8.35	350 -> 198	350 -> 96.9
39.	Chlorpyrifos-methyl	7.88	324 -> 125.1	322 -> 125.1
40.	Chlortoluron	6.31	213.1 -> 72.2	213.1 -> 46.2
41.	Cinidon-ethyl	8.71	394.1 -> 348.1	394.1 -> 107
42.	Clethodim	5.81	360 -> 164	360 -> 268
43.	Clofentezine	8.27	303 -> 138	303 -> 102
44.	Clomazone	7.04	240.1 -> 125	240.1 -> 89.1
45.	Clothianidin	3.35	250 -> 169.1	250 -> 132
46.	Cyanazine	5.51	241.2 -> 214.2	241.2 -> 104.1
47.	Cyazofamid	7.4	325 -> 108	325 -> 261
48.	Cycluron	6.71	199.1 -> 89.1	199.1 -> 89
49.	Cymoxanil	3.91	199 -> 128	199 -> 111
50.	Cyproconazole (isomer 1)	7.45	292.2 -> 70.2	292.2 -> 125.2
51.	Cyproconazole (isomer 2)	7.44	292.1 -> 70.2	292.1 -> 125.2
52.	Cyprodinil	8.15	226 -> 93	226 -> 77
53.	Cyromazine	2.63	167.2 -> 85.1	167.2 -> 68.2
54.	Demeton-S-methyl	2.9	230.9 -> 89.1	230.9 -> 61
55.	Demeton-S-methyl-sulfon	5.6	262.9 -> 108.9	262.9 -> 169
56.	Desethyl-atrazine	3.9	188.1 -> 146.2	188.1 -> 104.1
57.	Desisopropyl-atrazine	3.2	174.1 -> 104.1	174.1 -> 96.1
58.	Desmedipham	6.23	318 -> 182	318 -> 136
59.	Desmethyl-pirimicarb	5.11	225 -> 72	225 -> 168.1
60.	Diazinon	7.88	305.1 -> 169.2	305.1 -> 97
61.	Dichlorvos	5.36	221 -> 109.1	223.1 -> 109.1
62.	Diclobutrazol	7.58	328 -> 70	328 -> 160
63.	Dicrotophos	3.47	238 -> 112	238 -> 193
64.	Diethofencarb	6.56	268 -> 226	268 -> 180
65.	Difenoconazole (isomer 1)	8.35	406.2 -> 251.1	408.2 -> 253.1
66.	Difenoconazole (isomer 2)	8.35	406.1 -> 251.1	408.1 -> 253.1
67.	Difenoxuron	6.78	287.2 -> 123.2	287.2 -> 72
68.	Diflubenzuron	7.62	311 -> 158.2	311 -> 141.2
69.	Dimethenamide	6.9	276.2 -> 244.1	276.2 -> 168.3
70.	Dimethoate	3.58	230 -> 125	230 -> 199.1
71.	Dimethomorph	7.22	388.2 -> 301.1	388.2 -> 165.2
72.	Dimoxystrobin	7.6	327.1 -> 205	327.1 -> 116
73.	Diniconazole	8.07	326 -> 70	326 -> 159
74.	Dinotefuran	2.02	203.1 -> 114.1	203.1 -> 129
75.	Dioxacarb	3.68	224 -> 123	224 -> 167.1
76.	Diphenylamin	7.03	170.1 -> 93	170.1 -> 92
77.	Disulfoton	6.08	275.1 -> 89	275.1 -> 61
78.	Diuron	6.7	233.1 -> 72	235.1 -> 72.1
79.	Edifenphos	6.66	311 -> 283	328 -> 283
80.	EPN	6.72	324 -> 157.1	324 -> 296
81.	Epoxiconazole	7.65	330 -> 121	330 -> 101
82.	Etaconazole	7.57	328.2 -> 159.1	328.2 -> 123
83.	Ethiofencarb	5.58	226.1 -> 106.9	226.1 -> 164.1
84.	Ethiofencarbsulfoxid	3.48	242 -> 107	242 -> 185.1
85.	Ethion	7.9	385 -> 199	385 -> 171
86.	Ethiprole	6.62	397.3 -> 351	397.3 -> 255.5
87.	Ethofenprox	9.66	394.1 -> 107.1	394.1 -> 177.2
88.	Ethofumesate	6.54	304 -> 121	304 -> 161
89.	Ethoprophos	5.98	243 -> 131	243 -> 97
90.	Ethoxyquin	7.4	218.1 -> 174	218.1 -> 160
91.	Etoxazole	9	360.1 -> 141	360.1 -> 57.2
92.	Famoxadone	7.72	392 -> 331	392 -> 238
93.	Fenamidone	6.65	312.1 -> 92.1	312.1 -> 65
94.	Fenamiphos	7.5	304.2 -> 217.1	304.2 -> 202.1
95.	Fenarimol	7.3	331 -> 268	331 -> 81
96.	Fenazaquin	9.91	307 -> 161	307 -> 147
97.	Fenbuconazole	7.57	337 -> 125	337 -> 70
98.	Fenhexamid	7.04	302 -> 97	302 -> 55
99.	Fenitrothion	6.4	278 -> 125.2	278 -> 109
100.	Fenoxycarb	7.53	302.2 -> 88.1	302.2 -> 116.2
101.	Fenpropimorph	9.84	304 -> 147	304 -> 117
102.	Fenpyroximate	9.29	422 -> 366.1	442 -> 135.1
103.	Fenthion	6.9	278.9 -> 169	278.9 -> 246.9
104.	Fenuron	3.85	165.1 -> 72.1	165.1 -> 46
105.	Flonicamid	2.25	230.1 -> 203.1	230.1 -> 174
106.	Flucarbazone	2.81	397.1 -> 130.1	397.1 -> 115
107.	Flufenacet	7.17	364.1 -> 152.2	364.1 -> 194.2
108.	Flufenoxuron	8.98	489.1 -> 158.2	489.1 -> 141.2
109.	Fluometuron	5.98	233.1 -> 72.1	233.1 -> 46
110.	Fluopicolid	7.2	385 -> 174.8	383 -> 173
111.	Fluoxastrobin	7.34	459.2 -> 427.2	459.2 -> 188
112.	Fluquinconazole	7.31	376 -> 349	376 -> 307
113.	Flusilazole	7.6	316 -> 247	316 -> 165
114.	Flutolanil	6.81	341.1 -> 242.1	341.1 -> 262.1
115.	Flutriafol	5.99	302 -> 123	302 -> 109
116.	Fonophos	5.9	247 -> 183	247 -> 201
117.	Forchlorfenuron	6.37	248 -> 93.1	248 -> 165.1
118.	Formetanate	4.48	222 -> 165.1	222 -> 120
119.	Fuberidazole	5.5	185 -> 157	185 -> 65
120.	Furalaxyl	6.62	302.1 -> 95.1	302.1 -> 242.1
121.	Furathiocarb	8.42	383.2 -> 195.2	383.2 -> 252.2
122.	Hexaconazole	7.95	314 -> 70	314 -> 159
123.	Hexaflumuron	8.42	461.1 -> 158.2	461.1 -> 141.1
124.	Hexythiazox	8.77	353 -> 228	353 -> 168
125.	Hydramethylnon	9.2	495.2 -> 323.1	495.2 -> 151
126.	Imazalil	8.1	297.1 -> 159.2	299.1 -> 161.2
127.	Imazapyr	7.3	262.2 -> 217.2	262.2 -> 202.2
128.	Imidacloprid	3.82	256.2 -> 209	256.2 -> 175.2
129.	Indoxacarb	8.03	528 -> 203	528 -> 56
130.	Ipconazole	8.33	334.2 -> 70	334.2 -> 125
131.	Iprodion	7.6	330.1 -> 244.9	332.1 -> 247
132.	Iprovalicarb	6.98	321.2 -> 119	321.2 -> 203.2
133.	Irgarol	7.72	254.2 -> 198.1	254.2 -> 83.2
134.	Isofenphos	6.66	314 -> 120	314 -> 162.1
135.	Isoprocarb	5.87	194.2 -> 95.1	194.2 -> 137.2
136.	Isoproturon	6.42	207.2 -> 72.1	207.2 -> 46.1
137.	Isoxaflutole	5.87	360.1 -> 251.1	360.1 -> 220.1
138.	Kresoxim-methyl	7.53	314 -> 116	314 -> 206
139.	Lenacil	6.5	235.3 -> 153.2	235.3 -> 136.2
140.	Linuron	6.99	249.1 -> 160	249.1 -> 182.1
141.	Lufenuron	8.83	511.1 -> 158.1	511.1 -> 141.2
142.	Malathion	6.83	331 -> 99.1	331 -> 127.1
143.	Mandipropamid	6.81	412.1 -> 328.1	412.1 -> 355.9
144.	Mefenacet	7.35	299 -> 148.1	299 -> 120.1
145.	Mepanipyrim	7.57	224 -> 106	224 -> 77
146.	Mepronil	6.86	270.1 -> 119.1	270.1 -> 228
147.	Metalaxyl	6.13	280.2 -> 220.2	280.2 -> 192.3
148.	Metconazole	8.01	320 -> 70	320 -> 125
149.	Methabenzthiazuron	6.56	222.1 -> 165.2	222.1 -> 150.3
150.	Methamidophos	1.06	142 -> 94	142 -> 125
151.	Methiocarb	6.82	226.1 -> 169.2	226.1 -> 121.1
152.	Methomyl	2.62	163.1 -> 88.1	163.1 -> 106
153.	Methoprotryne	6.95	272.2 -> 240.2	272.2 -> 198
154.	Methoxyfenozide	6.9	369 -> 149	369 -> 133
155.	Metobromuron	6.22	259 -> 170.2	259 -> 148.2
156.	Metolachlor	7.5	284.2 -> 252.2	284.2 -> 176.2
157.	Metoxuron	5.1	229 -> 72.1	229 -> 156.1
158.	Metribuzin	5.14	215.1 -> 187.2	215.1 -> 84.1
159.	Mevinphos	4.29	225 -> 127	225 -> 193
160.	Mexacarbate	7.02	223.2 -> 166.2	223.2 -> 151
161.	Milbemectin A3	10.3	546.4 -> 511.3	546.4 -> 493.3
162.	Milbemectin A4	10.5	560.4 -> 525.4	560.4 -> 55.2
163.	Molinate	7.3	188.2 -> 126.2	188.2 -> 55.1
164.	Monocrotophos	2.9	224 -> 127	224 -> 98
165.	Monolinuron	5.93	215.1 -> 126.1	215.1 -> 99
166.	Monuron	5.7	199.2 -> 72.2	199.2 -> 126.3
167.	Myclobutanil	7.17	289 -> 70	289 -> 125
168.	Neburon	7.65	275 -> 88	275 -> 114
169.	Nitenpyram	2.55	271.2 -> 126.1	271.2 -> 237.2
170.	Novaluron	8.38	493 -> 158.1	493 -> 141.1
171.	Nuarimol	6.7	315 -> 252	315 -> 81
172.	Omethoate	1.69	214 -> 124.9	214 -> 182.8
173.	Oxadixyl	4.85	279.2 -> 219.2	279.2 -> 132.1
174.	OxamyI	2.35	237.1 -> 72.1	237.1 -> 90.1
175.	Oxydemeton-methyl	3.1	247 -> 169	247 -> 109
176.	Paclobutrazol	6.82	294 -> 70	294 -> 125
177.	Parathion-ethyl	6.7	292.1 -> 236.2	292.1 -> 94.1
178.	Parathion-methyl	7.6	263.9 -> 232.1	263.9 -> 125
179.	Penconazole	8.01	284 -> 159	284 -> 70
180.	Pencycuron	8.1	329.1 -> 125.1	331.2 -> 127
181.	Phenmedipham	6.35	301.1 -> 136	301.1 -> 168.1
182.	Phenthoate	7	321 -> 163	321 -> 79
183.	Phosmet	6.7	318 -> 160	318 -> 133
184.	Phoxim	7.9	299.1 -> 129.1	299.1 -> 77.1
185.	Picoxystrobin	7.44	368 -> 145	368 -> 205
186.	Pinoxaden	7.99	401.3 -> 317.2	401.1 -> 57
187.	Piperonyl butoxide	8.62	356.2 -> 177.2	356.2 -> 119
188.	Pirimicarb	6.29	239.2 -> 72.1	239.2 -> 182.2
189.	Pirimicarb- desmethylformamido	6.4	253.2 -> 72.1	253.2 -> 225.3
190.	Pirimiphos-ethyl	7.48	334 -> 198.1	334 -> 182.1
191.	Prochloraz	8.29	376.1 -> 308	376.1 -> 70.1
192.	Promecarb	6.86	208.2 -> 109.1	208.2 -> 151.1
193.	Prometon	6.86	226.1 -> 142.1	226.1 -> 86
194.	Prometryn	7.4	242.2 -> 200.1	242.2 -> 158.1
195.	Propachlor	6.2	212.2 -> 170.1	212.2 -> 94.1
196.	Propamocarb	6.61	189.2 -> 102.2	189.2 -> 73.9
197.	Propargite	8.79	368 -> 231	368 -> 175
198.	Propazine	6.9	230.1 -> 146.1	230.1 -> 188.1
199.	Propham	5.78	180 -> 138	180 -> 120
200.	Propiconazole	7.98	342.1 -> 159.1	342.1 -> 69.1
201.	Propoxur	5.03	210.1 -> 111	210.1 -> 168.1
202.	Prosulfocarb	8.5	252.3 -> 91.1	252.3 -> 128.1
203.	py Cinerin I	9	317.2 -> 149	317.2 -> 106.9
204.	py Cinerin II	8.2	361.2 -> 149	361.2 -> 106.9
205.	Pymetrozin	3.61	218 -> 105	218 -> 78
206.	Pyracarbolid	5.4	218.2 -> 125	218.2 -> 97
207.	Pyraclostrobin	7.95	388 -> 194	388 -> 163
208.	Pyrazophos	7.8	374 -> 222	374 -> 194
209.	Pyrethrin I	8.9	329.2 -> 160.9	329.2 -> 132.9
210.	Pyrethrin II	8.3	373.1 -> 160.9	373.1 -> 308.9
211.	Pyridaben	9.33	365 -> 147	365 -> 309
212.	Pyridaphenthion	7.8	341 -> 189	341 -> 205
213.	Pyrimethanil	7.24	200 -> 107	200 -> 82
214.	Pyriproxyfen	8.72	322 -> 96	322 -> 185
215.	Quinalphos	6.7	299 -> 147	299 -> 163
216.	Quinoxyfen	9.12	308 -> 197	308 -> 162
217.	Rotenone	7.61	395 -> 213	395 -> 192
218.	Secbumeton	6.85	226.2 -> 170.1	226.2 -> 100
219.	Siduron	6.55	233.3 -> 137.2	233.3 -> 94
220.	Simetryn	6.36	214 -> 124	214 -> 144
221.	Spinosyn A	11.3	732.6 -> 142.1	732.6 -> 98
222.	Spinosyn D	11.6	746.6 -> 142.1	746.6 -> 98
223.	Spirodiclofen	8.96	411.3 -> 313.2	411.3 -> 213.1
224.	Spiromesifen	8.8	371.3 -> 273	371.3 -> 255
225.	Spiroxamine (isomer 1)	10.7; 11	298.4 -> 144.2	298.4 -> 100.2
226.	Spiroxamine (isomer 2)	10.7; 11	298.3 -> 144.2	298.3 -> 100.2
227.	Sulfentrazone	4.77	387 -> 307.1	387 -> 146
228.	Sulfotep-ethyl	7	323 -> 115	323 -> 171.1
229.	Sulprofos	7	323 -> 219	323 -> 247
230.	Tebuconazole	7.8	308 -> 70	308 -> 125
231.	Tebufenozide	7.39	353.1 -> 133.1	353.1 -> 297.1
232.	Tebufenpyrad	8.56	334 -> 117	334 -> 145
233.	Tebuthiuron	5.71	229.2 -> 172.4	229.2 -> 116.1
234.	Teflubenzuron	8.81	381.1 -> 141.2	381.1 -> 158.2
235.	Terbufos	6.5	289 -> 103	289 -> 57
236.	Terbumeton	6.84	226 -> 170	226 -> 114
237.	Terbutryn	7.57	242.2 -> 186.1	242.2 -> 68.1
238.	Tetraconazole	7.3	372 -> 159	372 -> 70
239.	Thiabendazole	5.71	202.1 -> 175.1	202.1 -> 131.2
240.	Thiacloprid	4.89	253.1 -> 126.1	253.1 -> 99.1
241.	Thiamethoxam	3.06	292 -> 211	292 -> 181
242.	Thidiazuron	5.18	221.2 -> 102.1	221.2 -> 127.9
243.	Thiobencarb	8.09	258.1 -> 125	258.1 -> 89
244.	Thiofanox	5.7	219 -> 57.1	219 -> 60.9
245.	Thiofanoxsulfon	3.4	251.1 -> 75.9	251.1 -> 57
246.	Thiofanoxsulfoxid	3.6	235.1 -> 104.1	235.1 -> 57
247.	Thiophanate-methyl	5.1	343 -> 151	343 -> 192
248.	Tolclofos-methyl	8	301 -> 175	301 -> 268.9
249.	Topramezone	1.73	364.1 -> 334.1	364.1 -> 125
250.	Triadimefon	6.94	294 -> 197	294 -> 225
251.	Triadimenol	7.04	296.1 -> 70.1	296.1 -> 227.2
252.	Tricyclazole	5.18	190 -> 163	190 -> 136
253.	Trifloxystrobin	8.09	409 -> 186	409 -> 206
254.	Triflumizole	8.47	346 -> 278	346 -> 73
255.	Triflumuron	7.94	359.1 -> 156.2	359.1 -> 139
256.	Triticonazole	7.38	318 -> 70	318 -> 125
257.	Uniconazole	7.4	292.2 -> 70.1	292.2 -> 43
258.	Vamidothion	3.75	288 -> 146	288 -> 118
259.	Zoxamide	7.7	336.1 -> 186.9	338.1 -> 188.7

LC_FF0490

Column

Ultra Aqueous C18 (cat.# 9178312)

Dimensions:

100 mm x 2.1 mm ID

Particle Size:

3 µm

Pore Size:

100 Å

Temp.:

35 °C

Sample

multicomponent pesticide standard

Diluent:

water

Conc.:

1 ppb each pesticide

Inj. Vol.:

10 µL

Mobile Phase

10 mM NH₄OAc in water

10 mM NH₄OAc in methanol

Time (min)	%B
0	20
8.0	90
12.0	100
14.8	100
14.9	20

Flow:

0.5 mL/min

Detector

Applied Biosystems/MDS Sciex LC/MS/MS

Model #:

4000 QTRAP^®

Ion Source:

TurboIonSpray^®

Ion Mode:

ESI+

Ion Spray Voltage:

5 kV

Gas 1:

50 psi (344.7 kPa)

Gas 2:

60 psi (413.7 kPa)

Source Temp.:

600 °C

Instrument

Shimadzu UFLCXR