Welcome to the New Restek.com! Take a tour of the new site and feel free to send us your feedback.

Your web browser will no longer be supported by Restek.com as of 30 June 2021.
To avoid any interruption in access or functionality, install a current-generation web browser now. Learn more.

Semivolatiles on Rxi-5ms (Split Injection)

GC_EV1418
PeakstR (min)
1.1,4-Dioxane-D8 (IS) 1.98
2.N-Nitrosodimethylamine2.15
3.Pyridine2.18
4.2-Fluorophenol (SS) 2.87
5.Phenol-D6 (SS) 3.48
6.Phenol3.49
7.Aniline3.54
8.bis-(2-chloroethyl)ether3.57
9.2-Chlorophenol3.62
10.1,3-Dichlorobenzene3.74
11.1,4-Dichlorobenzene-D4 (IS) 3.76
12.1,4-Dichlorobenzene3.77
13.Benzyl Alcohol3.86
14.1,2-Dichlorobenzene3.92
15.2-Methylphenol3.95
16.Bis(2-Chloroisopropyl)ether3.98
17.4-Methylphenol4.06
18.3-Methylphenol4.06
19.N-Nitrosodi-N-propylamine4.09
20.Hexachloroethane4.17
21.Nitrobenzene-D5 (SS) 4.21
22.Nitrobenzene4.22
23.Isophorone4.41
24.2-Nitrophenol4.49
25.2,4-Dimethylphenol4.5
26.Benzoic acid4.54
27.Bis(2-chloroethoxy)methane4.58
28.2,4-Dichlorophenol4.67
29.1,2,4-Trichlorobenzene4.76
30.Naphthalene-D8 (IS) 4.79
31.Naphthalene4.81
PeakstR (min)
32.4-Chloroaniline4.86
33.Hexachlorobutadiene4.96
34.4-Chloro-3-methylphenol5.26
35.2-Methylnaphthalene5.4
36.1-Methylnaphthalene5.49
37.Hexachlorocyclopentadiene5.6
38.2,4,6-Trichlorophenol5.66
39.2,4,5-Trichlorophenol5.69
40.2-Fluorobiphenyl (SS) 5.73
41.2-Chloronaphthalene5.82
42.2-Nitroaniline5.93
43.1,4-Dinitrobenzene6.02
44.Dimethyl phthalate6.11
45.1,3-Dinitrobenzene6.12
46.2,6-Dinitrotoluene6.17
47.Acenaphthylene6.19
48.1,2-Dinitrobenzene6.23
49.3-Nitroaniline6.29
50.Acenaphthene-D10 (IS) 6.33
51.Acenaphthene6.35
52.2,4-Dinitrophenol6.38
53.4-Nitrophenol6.42
54.Dibenzofuran6.49
55.2,4-Dinitrotoluene6.51
56.2,3,5,6-Tetrachlorophenol6.59
57.2,3,4,6-Tetrachlorophenol6.63
58.Diethyl Phthalate6.72
59.4-Chlorophenyl phenyl ether6.79
60.Fluorene6.8
61.4-Nitroaniline6.83
62.4,6-Dinitro-2-methylphenol6.87
PeakstR (min)
63.N-Nitrosodiphenylamine (as Diphenylamine)6.89
64.N,N'-Diphenylhydrazine (as Azobenzene)6.93
65.2,4,6-Tribromophenol (SS) 7.02
66.4-Bromophenyl phenyl ether7.22
67.Hexachlorobenzene7.36
68.Pentachlorophenol7.51
69.Phenanthrene-D10 (IS) 7.62
70.Phenanthrene7.64
71.Anthracene7.68
72.Carbazole7.82
73.di-n-Butyl phthalate8.16
74.Fluoranthene8.73
75.Benzidine8.85
76.Pyrene-D10 (SS) 8.95
77.Pyrene8.97
78.p-Terphenyl-D14 (SS) 9.14
79.3,3'-Dimethylbenzidine9.74
80.Butyl benzyl phthalate9.79
81.Bis(2-ethylhexyl) adipate9.89
82.3,3'-Dichlorobenzidine10.6
83.Benz[a]anthracene10.62
84.Chrysene-D12 (IS) 10.65
85.Chrysene10.69
86.Bis(2-ethylhexyl) phthalate10.8
87.Di-n-octyl phthalate12.14
88.Benzo[b]fluoranthene12.93
89.Benzo[k]fluoranthene12.99
90.Benzo[a]pyrene13.77
91.Perylene-D12 (IS) 13.93
92.Indeno[1,2,3-cd]pyrene16.56
93.Dibenz[a,h]anthracene16.62
94.Benzo[ghi]perylene17
ColumnRxi-5ms, 30 m, 0.25 mm ID, 0.25 µm (cat.# 13423)
Standard/SampleRevised SV internal standard mix (cat.# 31886)
Revised B/N surrogate mix (cat.# 31888)
Acid surrogate mix (4/89 SOW) (cat.# 31063)
8270 MegaMix (cat.# 31850)
8270 Benzidines mix (cat.# 31852)
Benzoic acid (cat.# 31879)
Diluent:Dichloromethane
Conc.:5.0 ng/µL (IS and SS concentrations are 20 ng/µL)
Injection
Inj. Vol.:1 µL split (split ratio 10:1)
Liner:Premium 4 mm Precision liner w/wool (cat.# 23305.5)
Inj. Temp.:275 °C
Oven
Oven Temp.:50 °C (hold 0.5 min) to 265 °C at 28 °C/min to 285 °C at 3 °C/min to 330 °C at 20 °C/min (hold 5 min)
Carrier GasHe, constant flow
Flow Rate:1.44 mL/min
DetectorMS
Mode:Scan
Scan Program:
GroupStart Time
(min)
Scan Range
(amu)
Scan Rate
(scans/sec)
11.535-5505.4
Transfer Line Temp.:280 °C
Analyzer Type:Quadrupole
Source Type:Extractor
Extractor Lens:9mm ID
Source Temp.:350 °C
Quad Temp.:200 °C
Electron Energy:70 eV
Tune Type:DFTPP
Ionization Mode:EI
InstrumentAgilent 7890B GC & 5977A MSD