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Pesticides on Ultra Aqueous C18

LC_FF0490
PeakstR (min)Transition 1Transition 2
1.Acephate1.27184.1 -> 143184.1 -> 125
2.Acetamiprid4.44223.2 -> 126.1223.2 -> 99.1
3.Acibenzolar-S-methyl7.22211 -> 136211 -> 140
4.Alanycarb7.91400.1 -> 238.2400.1 -> 91.1
5.Aldicarb4.49208.2 -> 116.1208.2 -> 89.1
6.Aldicarb sulfone2.03223.1 -> 86.1223.1 -> 148
7.Aldicarb sulfoxide2.2207.1 -> 132.1207.1 -> 89.1
8.Ametryn6.96228.1 -> 186.1228.1 -> 96
9.Aminocarb5.37209.1 -> 137.1209.1 -> 152.1
10.Avermectin B1a11.2890.5 -> 305890.5 -> 145
11.Avermectin B1b11.4876.5 -> 291876.5 -> 145
12.Azoxystrobin6.78404.1 -> 372.1404.1 -> 344.1
13.Benalaxyl7.78326.2 -> 148.2326.2 -> 91.1
14.Bendiocarb5.1224.2 -> 109.2224.2 -> 167.2
15.Benfuracarb8.33411.2 -> 195.1411.2 -> 252.1
16.Benthiavalicarb6.87382.1 -> 116382.1 -> 180.1
17.Benthiavalicarb-isopropyl6.87382.1 -> 196.8382.1 -> 179.9
18.Benzoximate7.98364 -> 199364 -> 105
19.Bitertanol7.98338 -> 70338 -> 269
20.Boscalid6.98343 -> 307343 -> 140
21.Bromuconazole (isomer 1)7.36378 -> 159.1378 -> 161
22.Bromuconazole (isomer 2)8.05378.1 -> 159.1378.1 -> 161
23.Bufencarb5.18222.2 -> 95.1222.2 -> 71
24.Bupirimate7.65317 -> 166317 -> 108
25.Buprofezin8.53306.2 -> 201.1306.2 -> 116.2
26.Butafenacil7.08492.2 -> 331.1492.2 -> 180.1
27.Butocarboxim4.4191.1 -> 75191.1 -> 116
28.Butocarboximsulfoxid2.1207 -> 74.9207 -> 90
29.Butoxycarboxim1.95223.1 -> 106223.1 -> 166
30.Carbaryl5.63202.1 -> 145202.1 -> 127
31.Carbendazim4.52192.2 -> 160.2192.2 -> 132.1
32.Carbetamide4.74237 -> 192237 -> 118
33.Carbofuran5.18222.2 -> 123.1222.2 -> 165.2
34.Carboxine5.61236 -> 143236 -> 87
35.Carfentrazone ethyl7.53412 -> 346412 -> 366
36.Chlorfluazuron9.18540 -> 158540 -> 519.7
37.Chloroxuron7.53291 -> 72291 -> 218
38.Chlorpyrifos8.35350 -> 198350 -> 96.9
39.Chlorpyriphos-methyl7.88324 -> 125.1322 -> 125.1
40.Chlortoluron6.31213.1 -> 72.2213.1 -> 46.2
41.Cinidon-ethyl8.71394.1 -> 348.1394.1 -> 107
42.Clethodim5.81360 -> 164360 -> 268
43.Clofentezine8.27303 -> 138303 -> 102
44.Clomazone7.04240.1 -> 125240.1 -> 89.1
45.Clothianidin3.35250 -> 169.1250 -> 132
46.Cyanazine5.51241.2 -> 214.2241.2 -> 104.1
47.Cyazofamid7.4325 -> 108325 -> 261
48.Cycluron6.71199.1 -> 89.1199.1 -> 89
49.Cymoxanil3.91199 -> 128199 -> 111
50.Cyproconazole (isomer 1)7.45292.2 -> 70.2292.2 -> 125.2
51.Cyproconazole (isomer 2)7.44292.1 -> 70.2292.1 -> 125.2
52.Cyprodinil8.15226 -> 93226 -> 77
53.Cyromazine2.63167.2 -> 85.1167.2 -> 68.2
54.Demeton-S-methyl2.9230.9 -> 89.1230.9 -> 61
55.Demeton-S-methylsulfon5.6262.9 -> 108.9262.9 -> 169
56.Desethyl-atrazine3.9188.1 -> 146.2188.1 -> 104.1
57.Desisopropylatrazine3.2174.1 -> 104.1174.1 -> 96.1
58.Desmedipham6.23318 -> 182318 -> 136
59.Desmethylpirimicarb5.11225 -> 72225 -> 168.1
60.Diazinon7.88305.1 -> 169.2305.1 -> 97
61.Dichlorvos5.36221 -> 109.1223.1 -> 109.1
62.Diclobutrazol7.58328 -> 70328 -> 160
63.Dicrotophos3.47238 -> 112238 -> 193
64.Diethofencarb6.56268 -> 226268 -> 180
65.Difenoconazole (isomer 1)8.35406.2 -> 251.1408.2 -> 253.1
66.Difenoconazole (isomer 2)8.35406.1 -> 251.1408.1 -> 253.1
67.Difenoxuron6.78287.2 -> 123.2287.2 -> 72
68.Diflubenzuron7.62311 -> 158.2311 -> 141.2
69.Dimethenamide6.9276.2 -> 244.1276.2 -> 168.3
70.Dimethoate3.58230 -> 125230 -> 199.1
71.Dimethomorph7.22388.2 -> 301.1388.2 -> 165.2
72.Dimoxystrobin7.6327.1 -> 205327.1 -> 116
73.Diniconazol8.07326 -> 70326 -> 159
74.Dinotefuran2.02203.1 -> 114.1203.1 -> 129
75.Dioxacarb3.68224 -> 123224 -> 167.1
76.Diphenylamin7.03170.1 -> 93170.1 -> 92
77.Disulfoton6.08275.1 -> 89275.1 -> 61
78.Diuron6.7233.1 -> 72235.1 -> 72.1
79.Edifenphos6.66311 -> 283328 -> 283
80.EPN6.72324 -> 157.1324 -> 296
81.Epoxiconazole7.65330 -> 121330 -> 101
82.Etaconazole7.57328.2 -> 159.1328.2 -> 123
83.Ethiofencarb5.58226.1 -> 106.9226.1 -> 164.1
84.Ethiofencarbsulfoxid3.48242 -> 107242 -> 185.1
85.Ethion7.9385 -> 199385 -> 171
86.Ethiprole6.62397.3 -> 351397.3 -> 255.5
87.Ethofenprox9.66394.1 -> 107.1394.1 -> 177.2
88.Ethofumesate6.54304 -> 121304 -> 161
89.Ethoprophos5.98243 -> 131243 -> 97
90.Ethoxyquin7.4218.1 -> 174218.1 -> 160
91.Etoxazole9360.1 -> 141360.1 -> 57.2
92.Famoxadone7.72392 -> 331392 -> 238
93.Fenamidone6.65312.1 -> 92.1312.1 -> 65
94.Fenamiphos7.5304.2 -> 217.1304.2 -> 202.1
95.Fenarimol7.3331 -> 268331 -> 81
96.Fenazaquin9.91307 -> 161307 -> 147
97.Fenbuconazole7.57337 -> 125337 -> 70
98.Fenhexamid7.04302 -> 97302 -> 55
99.Fenitrothion6.4278 -> 125.2278 -> 109
100.Fenoxycarb7.53302.2 -> 88.1302.2 -> 116.2
101.Fenpropimorph9.84304 -> 147304 -> 117
102.fenpyroximate9.29422 -> 366.1442 -> 135.1
103.Fenthion6.9278.9 -> 169278.9 -> 246.9
104.Fenuron3.85165.1 -> 72.1165.1 -> 46
105.Flonicamid2.25230.1 -> 203.1230.1 -> 174
106.Flucarbazone2.81397.1 -> 130.1397.1 -> 115
107.Flufenacet7.17364.1 -> 152.2364.1 -> 194.2
108.Flufenoxuron8.98489.1 -> 158.2489.1 -> 141.2
109.Fluometuron5.98233.1 -> 72.1233.1 -> 46
110.Fluopicolide7.2385 -> 174.8383 -> 173
111.Fluoxastrobin7.34459.2 -> 427.2459.2 -> 188
112.Fluquinconazole7.31376 -> 349376 -> 307
113.Flusilazole7.6316 -> 247316 -> 165
114.Flutolanil6.81341.1 -> 242.1341.1 -> 262.1
115.Flutriafol5.99302 -> 123302 -> 109
116.Fonophos5.9247 -> 183247 -> 201
117.Forchlorfenuron6.37248 -> 93.1248 -> 165.1
118.Formetanate4.48222 -> 165.1222 -> 120
119.Fuberidazole5.5185 -> 157185 -> 65
120.Furalaxyl6.62302.1 -> 95.1302.1 -> 242.1
121.Furathiocarb8.42383.2 -> 195.2383.2 -> 252.2
122.Hexaconazole7.95314 -> 70314 -> 159
123.Hexaflumuron8.42461.1 -> 158.2461.1 -> 141.1
124.Hexythiazox8.77353 -> 228353 -> 168
125.Hydramethylnon9.2495.2 -> 323.1495.2 -> 151
126.Imazalil8.1297.1 -> 159.2299.1 -> 161.2
127.Imazapyr7.3262.2 -> 217.2262.2 -> 202.2
128.Imidacloprid3.82256.2 -> 209256.2 -> 175.2
129.Indoxacarb8.03528 -> 203528 -> 56
PeakstR (min)Transition 1Transition 2
130.Ipconazole8.33334.2 -> 70334.2 -> 125
131.Iprodion7.6330.1 -> 244.9332.1 -> 247
132.Iprovalicarb6.98321.2 -> 119321.2 -> 203.2
133.Irgarol7.72254.2 -> 198.1254.2 -> 83.2
134.Isofenphos6.66314 -> 120314 -> 162.1
135.Isoprocarb5.87194.2 -> 95.1194.2 -> 137.2
136.Isoproturon6.42207.2 -> 72.1207.2 -> 46.1
137.Isoxaflutole5.87360.1 -> 251.1360.1 -> 220.1
138.Kresoxim-methyl7.53314 -> 116314 -> 206
139.Lenacil6.5235.3 -> 153.2235.3 -> 136.2
140.Linuron6.99249.1 -> 160249.1 -> 182.1
141.Lufenuron8.83511.1 -> 158.1511.1 -> 141.2
142.Malathion6.83331 -> 99.1331 -> 127.1
143.Mandipropamid6.81412.1 -> 328.1412.1 -> 355.9
144.Mefenacet7.35299 -> 148.1299 -> 120.1
145.Mepanipyrim7.57224 -> 106224 -> 77
146.Mepronil6.86270.1 -> 119.1270.1 -> 228
147.Metalaxyl6.13280.2 -> 220.2280.2 -> 192.3
148.Metconazole8.01320 -> 70320 -> 125
149.Methabenzthiazuron6.56222.1 -> 165.2222.1 -> 150.3
150.Methamidophos1.06142 -> 94142 -> 125
151.Methiocarb6.82226.1 -> 169.2226.1 -> 121.1
152.Methomyl2.62163.1 -> 88.1163.1 -> 106
153.Methoprotryne6.95272.2 -> 240.2272.2 -> 198
154.Methoxyfenozide6.9369 -> 149369 -> 133
155.Metobromuron6.22259 -> 170.2259 -> 148.2
156.Metolachlor7.5284.2 -> 252.2284.2 -> 176.2
157.Metoxuron5.1229 -> 72.1229 -> 156.1
158.Metribuzin5.14215.1 -> 187.2215.1 -> 84.1
159.Mevinphos4.29225 -> 127225 -> 193
160.Mexacarbate7.02223.2 -> 166.2223.2 -> 151
161.Milbemectin A310.3546.4 -> 511.3546.4 -> 493.3
162.Milbemectin A410.5560.4 -> 525.4560.4 -> 55.2
163.Molinate7.3188.2 -> 126.2188.2 -> 55.1
164.Monocrotophos2.9224 -> 127224 -> 98
165.Monolinuron5.93215.1 -> 126.1215.1 -> 99
166.Monuron5.7199.2 -> 72.2199.2 -> 126.3
167.Myclobutanil7.17289 -> 70289 -> 125
168.Neburon7.65275 -> 88275 -> 114
169.Nitenpyram2.55271.2 -> 126.1271.2 -> 237.2
170.Novaluron8.38493 -> 158.1493 -> 141.1
171.Nuarimol6.7315 -> 252315 -> 81
172.Omethoate1.69214 -> 124.9214 -> 182.8
173.Oxadixyl4.85279.2 -> 219.2279.2 -> 132.1
174.Oxamyl2.35237.1 -> 72.1237.1 -> 90.1
175.Oxydemeton-methyl3.1247 -> 169247 -> 109
176.Paclobutrazol6.82294 -> 70294 -> 125
177.Parathion-ethyl6.7292.1 -> 236.2292.1 -> 94.1
178.Parathion-methyl7.6263.9 -> 232.1263.9 -> 125
179.Penconazole8.01284 -> 159284 -> 70
180.Pencycuron8.1329.1 -> 125.1331.2 -> 127
181.Phenmedipham6.35301.1 -> 136301.1 -> 168.1
182.Phenthoate7321 -> 163321 -> 79
183.Phosmet6.7318 -> 160318 -> 133
184.Phoxim7.9299.1 -> 129.1299.1 -> 77.1
185.Picoxystrobin7.44368 -> 145368 -> 205
186.Pinoxaden7.99401.3 -> 317.2401.1 -> 57
187.Piperonyl butoxide8.62356.2 -> 177.2356.2 -> 119
188.Pirimicarb6.29239.2 -> 72.1239.2 -> 182.2
189.Pirimicarb- desmethylformamido6.4253.2 -> 72.1253.2 -> 225.3
190.Pirimiphos-ethyl7.48334 -> 198.1334 -> 182.1
191.Prochloraz8.29376.1 -> 308376.1 -> 70.1
192.Promecarb6.86208.2 -> 109.1208.2 -> 151.1
193.Prometon6.86226.1 -> 142.1226.1 -> 86
194.Prometryn7.4242.2 -> 200.1242.2 -> 158.1
195.Propachlor6.2212.2 -> 170.1212.2 -> 94.1
196.Propamocarb6.61189.2 -> 102.2189.2 -> 73.9
197.Propargite8.79368 -> 231368 -> 175
198.Propazine6.9230.1 -> 146.1230.1 -> 188.1
199.Propham5.78180 -> 138180 -> 120
200.Propiconazole7.98342.1 -> 159.1342.1 -> 69.1
201.Propoxur5.03210.1 -> 111210.1 -> 168.1
202.Prosulfocarb8.5252.3 -> 91.1252.3 -> 128.1
203.py Cinerin I9317.2 -> 149317.2 -> 106.9
204.py Cinerin II8.2361.2 -> 149361.2 -> 106.9
205.Pymetrozin3.61218 -> 105218 -> 78
206.Pyracarbolid5.4218.2 -> 125218.2 -> 97
207.Pyraclostrobin7.95388 -> 194388 -> 163
208.Pyrazophos7.8374 -> 222374 -> 194
209.Pyrethrin I8.9329.2 -> 160.9329.2 -> 132.9
210.Pyrethrin II8.3373.1 -> 160.9373.1 -> 308.9
211.Pyridaben9.33365 -> 147365 -> 309
212.Pyridaphenthion7.8341 -> 189341 -> 205
213.Pyrimethanil7.24200 -> 107200 -> 82
214.Pyriproxyfen8.72322 -> 96322 -> 185
215.Quinalphos6.7299 -> 147299 -> 163
216.Quinoxyfen9.12308 -> 197308 -> 162
217.Rotenone7.61395 -> 213395 -> 192
218.Secbumeton6.85226.2 -> 170.1226.2 -> 100
219.Siduron6.55233.3 -> 137.2233.3 -> 94
220.Simetryn6.36214 -> 124214 -> 144
221.Spinosyn A11.3732.6 -> 142.1732.6 -> 98
222.Spinosyn D11.6746.6 -> 142.1746.6 -> 98
223.Spirodiclofen8.96411.3 -> 313.2411.3 -> 213.1
224.Spiromesifen8.8371.3 -> 273371.3 -> 255
225.Spiroxamine (isomer 1)10.7; 11298.4 -> 144.2298.4 -> 100.2
226.Spiroxamine (isomer 2)10.7; 11298.3 -> 144.2298.3 -> 100.2
227.Sulfentrazone4.77387 -> 307.1387 -> 146
228.Sulfotep-ethyl7323 -> 115323 -> 171.1
229.Sulprofos7323 -> 219323 -> 247
230.Tebuconazole7.8308 -> 70308 -> 125
231.Tebufenozide7.39353.1 -> 133.1353.1 -> 297.1
232.Tebufenpyrad8.56334 -> 117334 -> 145
233.Tebuthiuron5.71229.2 -> 172.4229.2 -> 116.1
234.Teflubenzuron8.81381.1 -> 141.2381.1 -> 158.2
235.Terbufos6.5289 -> 103289 -> 57
236.Terbumeton6.84226 -> 170226 -> 114
237.Terbutryn7.57242.2 -> 186.1242.2 -> 68.1
238.Tetraconazole7.3372 -> 159372 -> 70
239.Thiabendazole5.71202.1 -> 175.1202.1 -> 131.2
240.Thiacloprid4.89253.1 -> 126.1253.1 -> 99.1
241.Thiamethoxam3.06292 -> 211292 -> 181
242.Thidiazuron5.18221.2 -> 102.1221.2 -> 127.9
243.Thiobencarb8.09258.1 -> 125258.1 -> 89
244.Thiofanox5.7219 -> 57.1219 -> 60.9
245.Thiofanoxsulfon3.4251.1 -> 75.9251.1 -> 57
246.Thiofanoxsulfoxid3.6235.1 -> 104.1235.1 -> 57
247.Thiophanate-methyl5.1343 -> 151343 -> 192
248.Tolclofos-methyl8301 -> 175301 -> 268.9
249.Topramezone1.73364.1 -> 334.1364.1 -> 125
250.Triadimefon6.94294 -> 197294 -> 225
251.Triadimenol7.04296.1 -> 70.1296.1 -> 227.2
252.Tricyclazole5.18190 -> 163190 -> 136
253.Trifloxystrobin8.09409 -> 186409 -> 206
254.Triflumizole8.47346 -> 278346 -> 73
255.Triflumuron7.94359.1 -> 156.2359.1 -> 139
256.Triticonazole7.38318 -> 70318 -> 125
257.Uniconazole7.4292.2 -> 70.1292.2 -> 43
258.Vamidothion3.75288 -> 146288 -> 118
259.Zoxamide7.7336.1 -> 186.9338.1 -> 188.7
ColumnUltra Aqueous C18 (cat.# 9178312)
Dimensions:100 mm x 2.1 mm ID
Particle Size:3 µm
Pore Size:100 Å
Temp.:35 °C
Samplemulticomponent pesticide standard
Diluent:water
Conc.:1 ppb each pesticide
Inj. Vol.:10 µL
Mobile Phase
A:10 mM NH4OAc in water
B:10 mM NH4OAc in methanol
Time (min)%B
0.0020
8.090
12.0100
14.8100
14.920
Flow:0.5 mL/min
DetectorApplied Biosystems/MDS Sciex LC/MS/MS
Model #:4000 QTRAP
Ion Source:TurboIonSpray®
Ion Mode:ESI+
Ion Spray Voltage:5 kV
Gas 1:50 psi (344.7 kPa)
Gas 2:60 psi (413.7 kPa)
Source Temp.:600 °C
InstrumentShimadzu UFLCXR