Semivolatiles With Appendix IX on Rxi-5ms by 8270D

	Peaks
1.	1,4-Dioxane-d8 (IS)
2.	1,4-Dioxane
3.	N-Nitrosodimethylamine
4.	Pyridine
5.	Ethyl methacrylate
6.	2-Picoline
7.	N-Nitrosomethylethylamine
8.	Methyl methanesulfonate
9.	2-Fluorophenol (SS)
10.	N-Nitrosodiethylamine
11.	Ethyl methanesulfonate
12.	Benzaldehyde
13.	Phenol-d6 (SS)
14.	Phenol
15.	Aniline
16.	Pentachloroethane
17.	Bis(2-chloroethyl) ether
18.	2-Chlorophenol
19.	1,3-Dichlorobenzene
20.	1,4-Dichlorobenzene-d4 (IS)
21.	1,4-Dichlorobenzene
22.	Benzyl alcohol
23.	1,2-Dichlorobenzene
24.	2-Methylphenol
25.	Bis(2-Chloroisopropyl)ether
26.	p-Cresol (4-methylphenol)
27.	m-Cresol (3-methylphenol)
28.	N-Nitrosopyrrolidine
29.	Acetophenone
30.	N-Nitrosodi-n-propylamine
31.	4-Nitrosomorpholine
32.	o-Toluidine
33.	Hexachloroethane
34.	Nitrobenzene-d5 (SS)
35.	Nitrobenzene
36.	N-Nitrosopiperidine
37.	Isophorone
38.	2-Nitrophenol
39.	2,4-Dimethylphenol
40.	Benzoic acid
41.	Bis(2-chloroethoxy)methane
42.	2,4-Dichlorophenol
43.	α,α-Dimethylphenethylamine (Phentermine)
44.	1,2,4-Trichlorobenzene
45.	Naphthalene-d8 (IS)
46.	Naphthalene
47.	4-Chloroaniline
48.	2,6-Dichlorophenol

	Peaks
49.	Hexachloropropene
50.	Hexachlorobutadiene
51.	Caprolactam
52.	N-Nitroso-N-butylamine
53.	1,4-Phenylenediamine
54.	4-Chloro-3-methylphenol
55.	Isosafrole I (isomer)
56.	2-Methylnaphthalene
57.	1-Methylnaphthalene
58.	Isosafrole II (isomer)
59.	1,2,4,5-Tetrachlorobenzene
60.	Hexachlorocyclopentadiene
61.	2,4,6-Trichlorophenol
62.	2,4,5-Trichlorophenol
63.	2-Fluorobiphenyl (SS)
64.	Safrole
65.	Biphenyl
66.	2-Chloronaphthalene
67.	1-Chloronaphthalene
68.	Diphenyl ether
69.	2-Nitroaniline
70.	1,4-Naphthoquinone
71.	1,4-Dinitrobenzene
72.	Dimethyl phthalate
73.	1,3-Dinitrobenzene
74.	2,6-Dinitrotoluene
75.	Acenaphthylene
76.	1,2-Dinitrobenzene
77.	3-Nitroaniline
78.	Acenaphthene-d10 (IS)
79.	Acenaphthene
80.	2,4-Dinitrophenol
81.	4-Nitrophenol
82.	Dibenzofuran
83.	2,4-Dinitrotoluene
84.	Pentachlorobenzene
85.	1-Naphthalamine
86.	2,3,5,6-Tetrachlorophenol
87.	2-Naphthalamine
88.	2,3,4,6-Tetrachlorophenol
89.	Diethyl phthalate
90.	4-Chlorophenyl phenyl ether
91.	Fluorene
92.	2-Methyl-5-nitroaniline
93.	4-Nitroaniline
94.	4,6-Dinitro-2-methylphenol
95.	N-Nitrosodiphenylamine
96.	1,2-Diphenylhydrazine (as Azobenzene)

Injection
Column	Rxi-5ms, 30 m, 0.25 mm ID, 0.25 µm (cat.# 13423)
Standard/Sample	Revised SV internal standard mix (cat.# 31886)
	Revised B/N surrogate mix (cat.# 31888)
	Acid surrogate mix (4/89 SOW) (cat.# 31063)
	8270 MegaMix (cat.# 31850)
	8270 Benzidines mix (cat.# 31852)
	Benzoic acid (cat.# 31879)
	Appendix IX mix #1, revised (cat.# 32459)
	Appendix IX mix #2 (cat.# 31806)
Diluent:	Dichloromethane
Conc.:	10 µg/mL (IS/SS 20 µg/mL)
Inj. Vol.:	1 µL split (split ratio 10:1)
Liner:	Premium 4 mm Precision liner w/wool (cat.# 23305.5)
Inj. Temp.:	275 °C
Split Vent Flow Rate:	14.4 mL/min
Oven
Oven Temp.:	50 °C (hold 0.5 min) to 265 °C at 28 °C/min to 285 °C at 3 °C/min to 330 °C at 25 °C/min (hold 1 min)
Carrier Gas	He, constant flow
Flow Rate:	1.44 mL/min

Detector

Mode:

Scan

Scan Program:

Group	Start Time (min)	Scan Range (amu)	Scan Rate (scans/sec)
1	1.35	35-550	5.36

Transfer Line Temp.:

290 °C

Analyzer Type:

Quadrupole

Source Temp.:

330 °C

Quad Temp.:

180 °C

Electron Energy:

70 eV

Solvent Delay Time:

1.35 min

Tune Type:

DFTPP

Ionization Mode:

Instrument

Agilent 7890A GC & 5975C MSD

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