LC Multiresidue Pesticide Standard #4 on Raptor ARC-18 by LC-MS/MS

	Peaks	t_R (min)	Precursor Ion	Product Ion 1	Product Ion 2
1.	Cyromazine	1.07	167.0	85.0	108.1
2.	Pymetrozine	1.35	218.0	105.0	79.0
3.	Dinotefuran	1.63	203.0	129.0	157.0
4.	Nitenpyram	1.68	271.1	125.9	224.9
5.	Flonicamid	1.89	230.0	203.1	174.1
6.	Imidacloprid	2.19	256.1	175.1	209.1
7.	Acetamiprid	2.40	223.0	126.0	56.1
8.	Cymoxanil	2.47	199.0	128.0	111.0
9.	Oxadixyl	2.77	279.0	219.0	132.0
10.	Carbetamide	2.79	237.0	118.0	192.0
11.	Secbumeton	2.93	226.2	100.2	170.2
12.	Prometon	2.93	226.0	86.3	184.3
13.	Terbumeton	2.97	226.1	114.1	170.1
14.	Imazalil	2.97	297.0	159.0	69.0
15.	Pyracarbolid	3.04	218.1	125.1	97.1
16.	Ametryn	3.22	228.1	68.1	186.1
17.	Pyrimethanil	3.51	200.0	107.0	82.0
18.	Spiroxamine isomer 1	3.56	298.0	144.0	100.0
19.	Metalaxyl	3.56	280.1	220.1	192.1
20.	Spiroxamine isomer 2	3.62	298.0	144.0	100.0
21.	Chlorantraniliprole	3.66	483.9	286.0	453.0
22.	Azoxystrobin	3.92	404.1	372.0	329.0
23.	Furalaxyl	3.96	302.1	270.1	242.2
24.	Fludioxonil	3.97	249.1	229.1	158.1
25.	Halofenozide	3.98	331.1	104.9	275.0
26.	Boscalid	4.06	342.9	307.0	139.9
27.	Mandipropamid	4.08	412.3	328.2	356.2
28.	Flutolanil	4.10	324.1	262.1	65.0
29.	Mepronil	4.20	270.1	91.0	119.0
30.	Myclobutanil	4.25	289.1	125.1	70.2
31.	Methoxyfenozide	4.29	369.1	149.1	313.2
32.	Triadimefon	4.33	294.1	197.2	69.3

	Peaks	t_R (min)	Precursor Ion	Product Ion 1	Product Ion 2
33.	Cyprodinil	4.34	226.0	93.0	108.0
34.	Mepanipyrim	4.40	224.1	106.0	77.0
35.	Fenhexamid	4.46	302.1	97.2	55.3
36.	Fluoxastrobin	4.46	459.0	427.0	188.0
37.	Butafenacil	4.48	492.0	180.0	331.0
38.	Picoxystrobin	4.78	368.0	145.1	205.1
39.	Rotenone	4.83	395.0	213.1	192.1
40.	Tebufenozide	4.86	353.1	133.0	297.1
41.	Dimoxystrobin	4.87	327.1	116.1	205.2
42.	Carfentrazone ethyl	4.89	412.0	346.0	266.0
43.	Kresoxim-methyl	4.90	314.1	206.0	116.0
44.	Zoxamide	5.06	336.0	187.1	159.0
45.	Famoxadone	5.09	392.2	331.1	238.0
46.	Prochloraz	5.14	376.0	308.0	70.1
47.	Benalaxyl	5.15	326.1	148.0	91.0
48.	Clofentezine	5.21	303.0	138.0	102.0
49.	Benzoximate	5.28	364.0	199.1	105.0
50.	Trifloxystrobin	5.50	409.0	186.0	145.0
51.	Fluazinam	5.77	464.8	373.0	338.1
52.	Metaflumizone	5.79	507.0	287.2	267.1
53.	Tebufenpyrad	5.85	334.0	117.0	145.0
54.	Pyriproxifen	5.91	322.1	96.0	227.1
55.	Piperonyl butoxide	5.93	356.3	176.9	119.0
56.	Quinoxyfen	6.03	308.0	197.0	161.9
57.	Amitraz	6.14	294.0	163.0	122.0
58.	Fenpyroximate	6.36	422.2	138.1	366.1
59.	Abamectin B1b	6.47	876.6	553.4	291.0
60.	Eprinomectin	6.53	914.6	186.0	154.0
61.	Abamectin B1a	6.61	890.5	305.2	567.3
62.	Fenazaquin	6.68	307.2	161.0	57.2
63.	Doramectin	6.81	916.6	331.2	593.4
64.	Moxidectin	6.81	640.5	498.3	528.4
65.	Ivermectin	7.00	892.6	569.4	551.4

Isomers are numbered sequentially based on elution order.

Column

Raptor ARC-18 (cat.# 9314A12)

Dimensions:

100 mm x 2.1 mm ID

Particle Size:

2.7 µm

Temp.:

50 °C

Standard/Sample

LC multiresidue pesticide standard #4 (cat.# 31975)

Diluent:

Water

Conc.:

20 ng/mL

Inj. Vol.:

5 µL

Mobile Phase

Water + 2 mM ammonium formate + 0.2% formic acid

Methanol + 2 mM ammonium formate + 0.2% formic acid

Time (min)	Flow (mL/min)	%A	%B
0.00	0.4	95	5
2.00	0.4	40	60
4.00	0.4	25	75
6.00	0.4	0	100
7.00	0.4	0	100
7.01	0.4	95	5
9.50	0.4	95	5

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