17 Polar Pesticide Panel on Raptor Polar X by LC-MS/MS

LC_FS0546

	Peaks	t_R (min)	Conc. (ng/mL)	Precursor Ion	Product Ion 1	Product Ion 2	Product Ion 3	Precursor 2	Product Ion 2
1.	Aminomethylphosphonic acid (AMPA)	0.805	200	110.1	79.1	63.1	81.1	-	-
2.	Bialophos	0.847	100	322.2	88.2	216.1	134.2	-	-
3.	Perchlorate	2.593	5	101.0	84.95	-	-	98.9	83
4.	Glufosinate	3.376	200	180.2	85.2	95.1	-	-	-
5.	3-(Methylphophinico) propionic acid (MPPA)	4.076	100	151.0	63.0	107.1	133.2	-	-
6.	Trifluoracetic acid (TFA)	4.423	20	113.0	69.1	19.1	-	-	-
7.	2-Hydroxyethane phosphonic acid (HEPA)	4.969	100	125.1	79.0	95.0	63	-	-
8.	Difluoroacetic acid (DFA)	5.018	200	95.0	51.1	-	-	-	-
9.	Chlorate	5.542	100	85.0	69.0	-	-	83.0	67.1
10.	Ethephon	5.564	200	143.1	107.2	-	-	-
11.	Glyphosate	6.113	200	168.1	63.1	79.1	-	-	-
12.	Bromide	6.423	2000	80.9	80.9	-	-	79.0	79.0
13.	Bromate	6.771	600	129.0	113	-	-	127	111.1
14.	N-acetyl AMPA	6.932	200	152.1	110.1	62.9	-	-	-
15.	Fosetyl aluminum	7.775	80	109.1	81.0	63.0	78.9	-	-
16.	Phosphonic acid	8.275	500	81.1	62.9	-	-	-	-
17.	N-acetyl glufosinate	9.980	200	222.2	136.1	134.1	59.0	-	-

Column

Raptor Polar X (cat.# 9311A32)

Dimensions:

30 mm x 2.1 mm ID

Particle Size:

2.7 µm

Pore Size:

90 Å

Temp.:

35 °C

Standard/Sample

Diluent:

Water

Inj. Vol.:

1 µL

Mobile Phase

A:

Water, 0.5% formic acid

B:

Acetonitrile, 0.5% formic acid

Time (min)	Flow (mL/min)	%A	%B
0.00	0.5	35	65
5.0	0.5	90	10
11.5	0.5	90	10
11.51	0.5	35	65
13	0.5	35	65

Detector	MS/MS
Ion Mode:	ESI-
Mode:	MRM
Instrument	UHPLC

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