Canadian Pesticide Standards on Raptor ARC-18

	Peaks	t_R (min)	Precursor Ion	Product Ion 1	Product Ion 2	Polarity
1.	Daminozide	1.2	161.1	143.2	44.1	+
2.	Acephate	2.5	184.0	143.1	95.1	+
3.	Dinotefuran	2.7	203.2	129.3	73.1	+
4.	Oxamyl	2.8	237.1	72.1	90.1	+
5.	Flonicamid	2.9	230.1	203.1	174.1	+
6.	Methomyl	2.9	163.1	88.1	106.1	+
7.	Thiamethoxam	2.9	292.0	211.1	181.1	+
8.	Imidacloprid	3.1	256.1	209.1	175.1	+
9.	Clothianidin	3.2	250.1	169.2	132.3	+
10.	Mevinphos I	3.3	225.1	127.1	193.2	+
11.	Dimethoate	3.3	230.0	199.1	125.1	+
12.	Acetamiprid	3.4	223.0	126.1	56.1	+
13.	Thiacloprid	3.6	253.0	126.0	90.1	+
14.	Mevinphos II	3.7	225.1	127.1	193.2	+
15.	Aldicarb	4.0	208.4	116.0	89.0	+
16.	Pirimicarb	4.1	239.2	72.1	182.3	+
17.	Thiophanate-methyl	4.5	343.1	151.3	311.2	+
18.	Dichlorvos	4.6	220.9	108.8	79.2	+
19.	Propoxur	4.7	210.1	111.1	93.1	+
20.	Carbofuran	4.7	222.1	123.1	165.2	+
21.	Carbaryl	5.0	202.1	145.1	127.1	+
22.	Imazalil	5.1	297.0	159.0	201.0	+
23.	Cyantraniliprole	5.2	475.1	285.9	444.2	+
24.	Azadirachtin	5.4	703.4	567.3	585.3	+
25.	Dodemorph	5.7	282.3	116.2	98.1	+
26.	Metalaxyl	5.9	280.2	220.2	192.2	+
27.	Naled	5.9	397.8	127.1	109.1	+
28.	Chlorantraniliprole	6.1	483.9	452.9	285.9	+
29.	Phosmet	6.1	318.0	160.1	77.2	+
30.	Spiroxamine	6.3	298.3	144.2	100.2	+
31.	Azoxystrobin	6.5	404.0	372.1	344.1	+
32.	Methiocarb	6.5	226.1	169.1	121.1	+
33.	Fludioxonil	6.6	274.0	180.0	126.0	-
34.	Dimethomorph I	6.7	388.2	301.2	165.3	+
35.	Boscalid	6.7	342.9	307.5	140.1	+
36.	Paclobutrazol	6.9	294.3	70.1	125.1	+
37.	Malathion	6.9	331.0	127.2	285.2	+
38.	Dimethomorph II	7.1	388.2	301.2	165.3	+
39.	Myclobutanil	7.2	289.1	70.1	125.1	+
40.	Bifenazate	7.4	301.0	198.1	170.2	+
41.	Fluopyram	7.5	397.1	173.2	208.3	+
42.	Cyprodinil	7.7	226.2	93.1	108.2	+
43.	Spirotetramat	8.0	374.2	216.1	302.1	+
44.	Ethoprophos	8.2	243.1	131.1	97.1	+
45.	Iprodione	8.4	330.1	245.0		+
46.	Iprodione (qualifier)	8.4	332.2	247.0		+
47.	Fipronil	8.5	436.8	331.8	251.9	-
48.	Fenoxycarb	8.8	302.1	88.1	116.1	+
49.	Tetrachlorvinphos	9.0	365.1	127.2	204.0	+
50.	Tebufenozide	9.0	353.2	133.2	297.2	+
51.	Kresoxim-methyl	9.1	314.2	267.2	222.2	+
52.	Fenthion	9.3	279.0	247.3	138.4	+
53.	Tebuconazole	9.4	308.1	70.1	125.1	+
54.	Benzovindiflupyr	9.5	398.2	378.0	322.1	+
55.	Diazinon	9.7	305.1	169.2	153.2	+
56.	Coumaphos	10.0	363.1	227.1	307.1	+
57.	Propiconazole	10.0	342.0	159.0	69.2	+
58.	Clofentezine	10.1	303.0	138.1	102.1	+
59.	Pyraclostrobin	10.3	388.2	194.4	163.4	+
60.	Spinosad (Spinosyn A)	10.6	732.4	142.2	98.1	+
61.	MGK-264 I	11.1	276.2	210.1	121.1	+
62.	Prallethrin	11.5	301.2	123.2	104.9	+
63.	Trifloxystrobin	11.6	409.2	186.1	145.1	+
64.	Spinosad (Spinosyn D)	11.7	746.5	142.3	98.4	+
65.	Spinetoram (Spinosyn J)	11.9	748.5	142.5	98.3	+
66.	Novaluron	12.0	493.2	158.1	140.9	+
67.	Pyrethrins (Pyrethrin II)	12.0	373.1	161.1	133.2	+
68.	MGK-264 II	12.0	276.2	210.1	121.1	+
69.	Buprofezin	12.3	306.2	201.4	57.1	+
70.	Teflubenzuron	12.4	379.0	338.9	196.1	-
71.	Spinetoram (Spinosyn L)	13.0	760.5	142.2	98.1	+
72.	Piperonyl butoxide	13.2	356.3	177.2	119.2	+
73.	Chlorpyrifos	13.4	349.9	198.0	97.1	+
74.	Allethrin	13.4	303.3	135.3	123.2	+
75.	Hexythiazox	13.6	353.1	228.1	168.1	+
76.	Etoxazole	14.5	360.2	141.1	304.2	+
77.	Spiromesifen	14.6	388.4	273.3	255.3	+
78.	Pyrethrins (Pyrethrin I)	15.0	329.2	161.2	133.2	+
79.	Cyfluthrin	15.2	451.1	191.2		+
80.	Cyfluthrin (qualifier)	15.2	453.1	193.2		+
81.	Spirodiclofen	15.5	411.2	71.2	43.4	+
82.	Cypermethrin	15.6	433.1	191.0	416.0	+
83.	(E)-Fenpyroximate	15.6	422.2	366.1	138.1	+
84.	Deltamethrin	15.9	523.1	280.8	505.9	+
85.	Fenvalerate	16.1	436.9	167.0		+
86.	Pyridaben	16.2	365.1	147.2	309.2	+
87.	Resmethrin	16.4	339.3	171.1	128.1	+
88.	Permethrin trans	16.5	408.3	183.2	355.1	+
89.	Methoprene	16.7	311.3	191.3	279.1	+
90.	Phenothrin (trans)	16.7	351.3	249.2	182.9	+
91.	Permethrin-cis	16.9	408.3	183.2	355.1	+
92.	Abamectin	16.9	890.5	305.4	567.4	+
93.	d-Phenothrin (cis)	16.9	351.3	249.2	182.9	+
94.	Etofenprox	17.0	394.3	177.2	359.3	+
95.	Bifenthrin	17.1	440.0	181.2	166.2	+
96.	Acequinocyl	18.2	402.3	343.2	189.0	+

Chromatogram corresponding to a standard prepared in acetonitrile at 100 ng/mL.

Column

Raptor ARC-18 (cat.# 9314A62)

Dimensions:

150 mm x 2.1 mm ID

Particle Size:

2.7 µm

Pore Size:

90 Å

Guard Column:

Raptor ARC-18 EXP guard column cartridge 5 mm, 2.1 mm ID, 2.7 µm (cat.# 9314A0252)

Temp.:

40 °C

Standard/Sample

Canadian pesticide standard #1 (cat.# 32593)

Canadian pesticide standard #2 (cat.# 32594)

Canadian pesticide standard #3 (cat.# 32595)

Canadian pesticide standard #4 (cat.# 32596)

Canadian pesticide standard #5 (cat.# 32597)

Canadian pesticide standard #6 (cat.# 32598)

Azadirachtin (cat.# 32599)

Dichlorvos (DDVP) (cat.# 32585)

Diluent:

Acetonitrile

Conc.:

100 ng/mL

Inj. Vol.:

1 µL

Mobile Phase

Water, 2 mM ammonium formate, 0.1% formic acid

Methanol, 2 mM ammonium formate, 0.1% formic acid

Time (min)	Flow (mL/min)	%A	%B
0.00	0.4	95	5
1.0	0.4	50	50
2.5	0.4	50	50
4.0	0.4	35	65
7.0	0.4	35	65
7.5	0.4	30	70
9.0	0.4	30	70
9.5	0.4	25	75
11.0	0.4	25	75
11.5	0.4	20	80
13.5	0.4	20	80
15.5	0.4	5	95
16.5	0.4	0	100
19.5	0.4	0	100
19.6	0.4	95	5

Detector	MS/MS
Ion Source:	Electrospray
Ion Mode:	ESI+/ESI-
Mode:	MRM
Instrument	Shimadzu 8045
Sample Preparation	Standards were aliquoted into 2 mL, screw-thread vials (cat.# 21143) and capped with short-cap, screw-vial closures (cat.# 24498).
Notes	Autosampler temperature: 10 °C Canadian pesticide standards are also available as a kit: Canadian pesticide kit (cat.# 32592)

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